Pick Colors from Screen
Click the "Pick Color ..." button from the main window to pick a color from the computer's screen.
Move the picker to the point that want to pick its color. Make sure the color will be in the red rectangle in the control panel.
Click the mouse, the color will be added into the palette in the control panel. You may add 28 colors to the palette.

Click the color in the palette on the control pannel, and click the "add to favorites" button to add it to the favorites collections, or click the "delete" button to remove it from the palette.
Keyboard Support
If you unchecked the item "Remove keyboard support" in the options dialog, then you may use keyboard to operate when picking a color.
Left Arrow : move mouse cursor left 1 pixel
Right Arrow : move mouse cursor right 1 pixel
Up Arrow : move mouse cursor up 1 pixel
Down Arrow : move mouse cursor down 1 pixel
Alt + Left Arrow : move mouse cursor left 5 pixels
Alt + Right Arrow : move mouse cursor right 5 pixels
Alt + Up Arrow : move mouse cursor up 5 pixels
Alt + Down Arrow : move mouse cursor down 5 pixels
Ctrl + Left Arrow : move mouse cursor left 10 pixels
Ctrl + Right Arrow : move mouse cursor right 10 pixels
Ctrl + Up Arrow : move mouse cursor up 10 pixels
Ctrl + Down Arrow : move mouse cursor down 10 pixels
Enter : pick the current pixel's color
Esc : return to the main window
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